(E)-[2-(1,3-Dithiolan-2-ylidene)hydrazinylidene](3-fluorophenyl)methyl 3-fluorobenzoate
نویسنده
چکیده
In the title compound, C17H12F2N2O2S2, the conformation of the dithia-cyclo-pentane ring is a half-chair, with a total puckering amplitude Q T = 0.460 (1) Å. π-π inter-actions [centroid-centroid distance = 3.585 (9) Å between the fluoro-phenyl rings of neighbouring mol-ecules] and C-H⋯N and C-H⋯O inter-actions help to stabilize the crystal structure and form ladders along the c axis.
منابع مشابه
[2-(1,3-Dithiolan-2-ylidene)-5-(4-methylphenyl)-3-oxopent-4-enoato-κO]triphenyltin(IV)
In the title compound, [Sn(C(6)H(5))(3)(C(17)H(17)O(3)S(2))], the Sn(IV) atom adopts a distorted tetra-hedral SnC(3)O geometry. A short intra-molecular Sn⋯O contact of 2.793 (2) Å also occurs.
متن کامل(3-Chlorophenyl)[(E)-2-(1,3-dithiolan-2-ylidene)hydrazinylidene]methyl 3-chlorobenzoate
In the title compound, C17H12Cl2N2O2S2, the di-thia-cyclo-pentane ring has an envelope conformation with one of the methyl-ene C atoms as the flap. The chloro-phenyl rings make a dihedral angle of 82.63 (7)°. In the crystal, π-π inter-actions between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.547 (2) Å] link the mol-ecules into inversion dimers. Weak non-classi...
متن کامل3-(1,3-Dithiolan-2-ylidene)-1-(4-methoxyphenyl)pyridine-2,4(1H,3H)-dione
In the title compound, C(15)H(13)NO(3)S(2), the dithiol-ane ring adopts a twisted conformation. The mol-ecule exhibits a V-shaped conformation, with a dihedral angle of 79.05 (7)° between the benzene ring and the pyridine ring. In the crystal, C-H⋯O inter-actions are observed.
متن کامل3-(1,3-Dithiolan-2-ylidene)-1-phenylpyridine-2,4(1H,3H)-dione
The title compound, C(14)H(11)NO(2)S(2), was synthesized by reaction of 2-(1,3-dithio-lan-2-yl-idene)-3-oxo-N-phenyl-butanamide with N,N'-dimethyl-formamide dimethyl acetal in N,N'-dimethyl-formamide. The mol-ecule exhibits a V-shaped conformation in the crystal, with a dihedral angle of 65.9 (2)° between the benzene and pyridine rings. In the crystal. C-H⋯O and C-H⋯S interactions are observed....
متن کاملN-[(E,Z)-1,3-Diphenylprop-2-enylidene]-N′-(1,3-dithiolan-2-ylidene)hydrazine
Mol-ecules of the title compound, C(18)H(16)N(2)S(2), exist as the (2E, 1'Z)-isomer. The 1,3-dithiol-ane ring has an envelope conformation; the atoms of the C-C bond are disordered over two positions with occupancies of 0.47 (7) and 0.53 (7). The structure exhibits inter-molecular C-H⋯S and C-H⋯π(arene) hydrogen bonds.
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